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Versus TePP and you can pentaphenylpyrrole (PPP), both TPM and you may TPM-Cl displayed lengthened emission frequencies. Because of its comparable chemical substances formations, this is not possible so you can feature the significant Stokes move so you can variations in the ability pit between the lower singlet happy condition (S1) and you can ground county (S0). We hence suggest that the new red emission corresponds to a minimal triplet happy condition (T1), which is lower than S1. 2, in which the contours are identical to their constant-county emission spectra, sharing the brand new much time life functions away from each other TPM and you may TPM-Cl. The newest lifetimes of your own TPM and you will TPM-Cl crystalline powders are 20.step one and you will 8.9 μs, respectively (Fig. S3 and you can Desk S1).
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Chongqing Wulong Karst Area, Wulong Karst Landscape
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